The half-life of \({_{92}^{238}}{{}}{{}}{U}{}\) undergoing α-decay is \(4.5\times 10^9\) years. What is the activity of \(1g\) sample of \({_{92}^{238}}{{}}{{}}{U}{}\) ?
Answer
\(R=1.23\times 10^4\mathit{Bq}\)
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Solution
Solution - The half-life of \({_{92}^{238}}{{}}{{}}{U}{}\) undergoing α-decay is \({T}_{1/2}=4.5\times {10}^{9}\;years\) or\(T_{1/2}=1.42\times 10^{17}s\)(By converting into seconds) Let\( R =\) activity of given sample. One mole of any isotope contains Avogadro’s number of atoms. Now we find number of atoms in \(1g\) of \({_{92}^{238}}{{}}{{}}{U}{}\) which is given by \(N=\frac{1}{238\times {10}^{-3}}\times 6.023\times {10}^{24}\;=\;25.3\times {10}^{20}\;\mathit{a}\mathit{t}\mathit{o}\mathit{m}\mathit{s}\) the decay rate \(R\) is given by \(R=\mathit{\lambda N}\) Now \(decay\;constant(\lambda )\;=\;\dfrac{0.693}{T{}_{\frac{1}{2}}}\) So, \(R=\left(\frac{0.693}{T_{1/2}}\right)N\) or \(R=\left(\frac{0.693}{T_{1/2}}\right)N\) On putting the values we have, \(R=\left(\frac{0.693}{1.42\times 10^{17}}\right)\times 25.3\times 10^{20}\) or \(R=1.23\times 10^4\mathit{Bq}\). Hence activity of given sample of uranium is\(R=1.23\times 10^4\mathit{Bq}\).
The rate of first order reaction is \(0.04\)\(mol\)\(L^{-1}s^{-1}\) at \(10 \)\(min\) and \(0.03\) mol \(L^{-1}s^{-1}\) at \(20\)\(min\) after initiation. Find the half-life of the reaction.
We are given the following atomic masses: \({_{92}^{238}}{{}}{{}}{U}{}=238.05079u\) \({_{90}^{234}}{{}}{{}}{Th}{}=234.04363u\) \({_{91}^{237}}{{}}{{}}{\mathit{Pa}}{}=237.05121u\) \({_2^4}{{}}{{}}{\mathit{He}}{}=4.00260u\) \({_1^1}{{}}{{}}{H}{}=1.00783u\) Here the symbol \(\mathit{Pa}\) is for the element protactinium \((Z=91).\) Calculate the energy released during the alpha decay of \({_{92}^{238}}{{}}{{}}{U}{}\) .
A hydrogenation reaction is carried out at \(500 K\). If the same reaction is carried out in the presence of a catalyst at the same rate, the temperature required is \(400 K\). Calculate the activation energy of the reaction, if the catalyst lowers the activation barrier by \(20\ kJ\ mol^{-1}\).
We are given the following atomic masses: \({_{92}^{238}}{{}}{{}}{U}{}=238.05079u\) \({_{90}^{234}}{{}}{{}}{Th}{}=234.04363u\) \({_{91}^{237}}{{}}{{}}{\mathit{Pa}}{}=237.05121u\) \({_2^4}{{}}{{}}{\mathit{He}}{}=4.00260u\) \({_1^1}{{}}{{}}{H}{}=1.00783u\) Here the symbol \(\mathit{Pa}\) is for the element protactinium \((Z=91).\) Show that \({_{92}^{238}}{{}}{{}}{U}{}\) can not spontaneously emit a proton.
Consider the following cell reaction. \(2Fe(s)+O_{2}(g)+4H^{+}(aq)\to 2Fe^{2+}(aq)+2H_{2}O(l),\)\(E^{o}=1.67V\) At \([Fe^{2+}]=10^{-3}M,P(O_{2})=0.1\ atm\) and \(pH=3\) , the cell potential at \(25^{\circ }C\) is ( )